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Vinyl-type polymerization of norbornene by a nickel-based catalyst with phosphoraneiminato ligands

โœ Scribed by Christian Mast; Matthias Krieger; Kurt Dehnicke; Andreas Greiner


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
59 KB
Volume
20
Category
Article
ISSN
1022-1336

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Polymerization with TMA-protected polar
โœ Sandra G. Correia; Maria M. Marques; Josรฉ R. Ascenso; Alejandro F. G. Ribeiro; P ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 160 KB

โฃ-Diimine Ni complexes (7, 8) were used as catalyst precursors with MAO in co-and terpolymerization of ethylene/propylene/โฃ-olefins with OH and COOH functional groups. Trimethylaluminium was used to protect the functional group of polar monomers. The presence of 5-hexen-1-ol seems to have no effect