## Abstract Pd(II) catalysts with nitrilo ligands and BF~4~^−^ counter ions give the best results in vinylic polymerization of norbornene. Absolute molecular weight determination of polynorbornene (PN) by means of light scattering and the three‐dimensional shape of PN were also investigated. By cor
✦ LIBER ✦
Vinyl-Type Addition Polymerization of Norbornene and Synthesis of Norbornene Macromonomers in the Presence of Ethylene Catalyzed by Cobalt(II)−Phosphine Complexes
✍ Scribed by Leone, Giuseppe; Boglia, Aldo; Boccia, Antonella Caterina; Scafati, Santolo Taglialatela; Bertini, Fabio; Ricci, Giovanni
- Book ID
- 127264065
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 937 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0024-9297
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## Abstract **Summary:** The polymerizations of ethyl vinyl ether, __n__‐butyl vinyl ether and isobutyl vinyl ether were investigated with a series of pyridine bis(imine) complexes of iron(II) and cobalt(II) in the presence of methylaluminoxane. The cobalt catalysts showed much higher activity and