## Abstract The polymerization of acrylonitrile was studied with a peroxydiphosphate–ascorbic acid redox system as the initiator. The rate of polymerization increased with increasing peroxydiphosphate concentration and the initiator exponent was computed to be 0.5. It also increased with increasing
✦ LIBER ✦
Vinyl polymerization initiated by peroxydiphosphate. XII. Polymerization of acrylamide and acrylic acid by peroxydiphosphate–sodium thiosulfate redox system
✍ Scribed by Lenka, Subasini ;Nayak, Padma L. ;Ray, Suparna
- Publisher
- John Wiley and Sons
- Year
- 1984
- Weight
- 248 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0360-6376
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The kinetics of aqueous polymerization of acrylamide (AM) and methacrylamide (MAM) have been studied using a potassium peroxydiphosphate (PDP/Mn(II) system in an inert atmosphere at 40¡C and at constant pH (1É30). The polymerization rate has been found to be proportional to the half power R p of PDP
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