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Vinyl Benzenes as Dienes in Mild Solid-Phase Diels−Alder Reactions †

✍ Scribed by Sun, Sengen; Turchi, Ignatius J.; Xu, Dawei; Murray, William V.


Book ID
126278801
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
99 KB
Volume
65
Category
Article
ISSN
0022-3263

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Vinyl-allenes as dienes in the Lewis aci
✍ David Regás; Marı́a M Afonso; Antonio Galindo; J.Antonio Palenzuela 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 115 KB

The Lewis acid-mediated, hetero Diels±Alder reaction of a vinyl-allene system with aldehydes as heterodienophiles has been carried out. In the cases studied, only two cycloadducts have been obtained, which correspond to the endo (major compound) and exo (minor compound) approach of the aldehyde thro