VIIIVIV3O3(PO4)3: A Novel Vanadium Phosphate for Selective Oxidation of Light Hydrocarbons
β Scribed by Hibst, Hartmut; Benser, Ernst; Glaum, Robert; Dross, Thomas
- Book ID
- 115475086
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 333 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0897-4756
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The antimony (III) phosphate, NaSb 3 O 2 (PO 4 ) 2 , is a framework structure built from Sb III and P V centers; orthorhombic, space group Pca2 1 (No. 29), a β«Ψβ¬ 13.944( 3), b β«Ψβ¬ 6.6822( 13), c β«Ψβ¬ 20.886(4) A > , V β«Ψβ¬ 1946.1(7) A > 3 , Z β«Ψβ¬ 8. Stereochemically active lone pairs of electrons asso
A new three-dimensional gallium phosphate, [NH 3 (CH 2 ) 4 NH 3 ] 2 [Ga 4 (HPO 4 ) 2 (PO 4 ) 3 (OH) 3 ] ' yH 2 O (y&5.4), has been synthesized under hydrothermal conditions at 433 K in the presence of 1,4-diaminobutane and its structure determined using room-temperature single-crystal X-ray di4racti