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Vicarious Nucleophilic Substitution (VNS) of Hydrogen in Azulenes

✍ Scribed by M??goikosza, Mieczyslaw ;Kuciak, Renata ;Wojciechowski, Krzysztof

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
416 KB
Volume
1994
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

Azulene reacts with carbanions bearing a leaving group according to the vicarious nucleophilic substitution (VNS) scheme. Treatment of 6‐chloroazulene with such carbanions affords the VNS reaction and nucleophilic aromatic substitution (S~N~Ar) products. magnified image

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