Vicarious nucleophilic substitution of hydrogen ortho to the nitro group by tertiary carbanions of α-chloroalkyl phenyl sulphones1

Vicarious Nucleophilic Substitution of H

Vicarious Nucleophilic Substitution of Hydrogen in Nitropyridines by α-Chloroalkyl Phenyl Sulfone Carbanions

✍ M??kosza, Mieczystaw ;Chylińska, Barbara ;Mudryk, Bogustaw 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 391 KB

## Abstract Nitropyridines and chloronitropyridines react with carbanions of α‐chloroalkyl phenyl sulfones yielding products of the vicarious nucleophilic substitution of hydrogen at positions __ortho__ and __para__ to the nitro group. A general rule that the vicarious substitution of hydrogen proc