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Vibronic Structure of the 3s and 3p Rydberg States of the Allyl Radical †

✍ Scribed by Gasser, Michael; Frey, Jann A.; Hostettler, Jonas M.; Bach, Andreas; Chen, Peter


Book ID
126933524
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
327 KB
Volume
114
Category
Article
ISSN
1089-5639

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Resonance enhanced multiphoton ionization spectroscopy, (2C1) REMPI, has been employed in jet cooled styrene vapors for the detection of Rydberg states. A resonance appears at 50,484 cm K1 and is interpreted as a 3p)HOMO Rydberg transition (dZ0.52). The 3s state was not detected in the REMPI experim