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Vibronic spectral behaviour of molecules. Theoretical analysis of the biphenyl phosphorescence

✍ Scribed by Klaus Gustav; Cornelia Seydenschwanz


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
274 KB
Volume
109
Category
Article
ISSN
0009-2614

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✦ Synopsis


The calculated vihronic strtrcture of the phosphorescence of biphenyl is presented and compared with the esperimental spwtrum. .4n sssigm~ent of the vibronic transitions for the msin peaks is @zn. The comparison between theory and esperimcnt is 53tisf;lctory.


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Theoretical vibronic T,+Sc "line" spectra of the isomeric phenylnaphthalenes, calculated within the Condon approach on the basis of completely optimized So and T, molecular geometries, are presented and compared with experimental phosphorescence spectra. The theory-experiment comparison is satisfact

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