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Vibronic relaxation in parabenzoquinone: Its effect on the decay rate of rotary spin echoes

✍ Scribed by C.A. van 't Hof; J. Schmidt

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
301 KB
Volume
36
Category
Article
ISSN
0009-2614

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✦ Synopsis

We have observed that the decay rates of rotary spin echoes in the lowest triplet state To of parabenzoquinone (PBQ) and toluquinonc (TQ) increase cxponentiaIly with the temperature. The activation erwigy in TQ is equal to the trap depth but in PBQ it corresponds with the energy differences between To and a hiher Lying vibratic Iewe1 T,. From the experimental data we obtain the rates for excitation to and decay fr0.m this escited vibronic lcvcl in PBQ.

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