Vibronic partial photoionization cross sections associated with the ejection of A 3σg electron in the O2 molecule
✍ Scribed by P. Morin; I. Nenner; P.M. Guyon; L.F.A. Ferreira; K. Ito
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 484 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Vlbroruc p~rlal cross sections assoclaed with the formatron of 0: bJZgand B 'T; ~13~s (3og') arc obrnmed m chr threshold region usmg timeaf-tlighr pholoclectron spccrroscopy assoclxted with pulsed synchro!ron rsdlstlon The b cross section reveals 3 strong resonsncr around 19 cV, prcv~ouslp observed by lluorcsccncc e~~;luon specuoscopy. The B cross sccCtlon sho\rs contnbutlons of two autolonlzing Rydbcrg S~XCS bclongmg 10 the swcs convcrgmg to 05 C'Z; Vrbnlional branchmgrauos for both elcctromc sues show large dcvlatlons from Fnnck-Condon &stribullons e\pccred ior a ample duect ioruauon mechamsm.