<p>This book is based mostly on the reports presented at the XVth International lahn-Teller Symposium on Vibronic Interactions in Crystals and Molecules and NATO Advanced Research Workshop Colossal Magnetoresistance and Vibronic Interactions that took place at Boston on August 16-22 of the year 2000
Vibronic Interactions in Molecules and Crystals
β Scribed by Professor Dr. Isaac B. Bersuker (auth.), Professor Dr. Isaac B. Bersuker, Dr. Sci. Victor Z. Polinger (eds.)
- Publisher
- Springer-Verlag Berlin Heidelberg
- Year
- 1989
- Tongue
- English
- Leaves
- 433
- Series
- Springer Series in Chemical Physics 49
- Edition
- 1
- Category
- Library
No coin nor oath required. For personal study only.
β¦ Synopsis
Vibronic interaction effects constitute a new field of investigation in the physics and chemistry of molecules and crystals that combines all the phenomena and laws originating from the mixing of different electronic states by nuclear displacements. This field is based on a new concept which goes beyond the separate descriptions of electronic and nuclear motions in the adiabatic approximation. Publications on this topic often appear under the title of the lahn-Thller effect, although the area of application of the new approach is much wider: the term vibronic interaction seems to be more appropriate to the field as a whole. The present understanding of the subject was reached only recently, during the last quarter of a century. As a result of intensive development of the theory and experiment, it was shown that the nonadiabatic mixing of close-in-energy elecΒ tronic states under nuclear displacements and the back influence of the modified electronic structure on the nuclear dynamics result in a series of new effects in the properties of molecules and crystals. The applications of the theory of vibronic inΒ of spectroscopy [including visible, ultraviolet, inΒ teractions cover the full range frared, Raman, EPR, NMR, nuclear quadrupole resonance (NQR), nuclear gamΒ ma resonance (NOR), photoelectron and x-ray spectroscopy], polarizability and magnetic susceptibility, scattering phenomena, ideal and impurity crystal physics and chemistry (including structural as well as ferroelectric phase transitions), stereochemistry and instability of molecular (including biological) systems, mechanisms of chemical reactions and catalysis.
β¦ Table of Contents
Front Matter....Pages I-XII
Introduction....Pages 1-4
Vibronic Interactions and the Jahn-Teller Theorem....Pages 5-30
Adiabatic Potentials....Pages 31-106
Solution of Vibronic Equations. Tunneling Splitting....Pages 107-208
Spectroscopic Manifestations of Vibronic Effects....Pages 209-316
Cooperative Phenomena. Structural Phase Transitions....Pages 317-379
Back Matter....Pages 380-422
β¦ Subjects
Atomic, Molecular, Optical and Plasma Physics;Crystallography
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