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Vibronic Interactions and Magnetic Dipole Effects in the Polarized Crystal Spectra of Diaquobismethoxyacetato Co (II)

✍ Scribed by P. D. Hu; A. L. Companion

Publisher: John Wiley and Sons
Year: 1973
Tongue: English
Weight: 506 KB
Volume: 56
Category: Article
ISSN: 0370-1972
DOI: 10.1002/pssb.2220560125

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✦ Synopsis

Abstract

Polarized absorption spectra of single crystals of diaquobismethoxyacetato Co(II) hare been measured at room and liquid nitrogen temperatures. The temperature dependence of oscillator strengths indicates that both vibronic and magnetic dipole transition mechanisms are operative. Selection rules within the C^2^t, point group permit assignment of major absorption peaks to transitions from a ^4^B~g~ ground state.

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