𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vibronic coupling in the pE″ Rydberg series of NH3

✍ Scribed by A. Staib; W. Domcke

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
520 KB
Volume
204
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The Jahn-Teller effect in the pE" Rydberg series of NH, is investigated within a simple multichannelquantumdefect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B 'E" (3p,,) band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg memhers are analyzed.

📜 SIMILAR VOLUMES

Vibronic coupling in the lowest singlet
Vibronic coupling in the lowest singlet state of dibenzofuran
✍ A. Bree; A.R. Lacey; I.G. Ross; R. Zwarich 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 449 KB

The lower&y absorption system of dibenzofuran vapour has been re-measured at high resolution. The origin band (0) and the prominent band at 0 + 445 have different contours, and so have opposite polarization. In the solid state, the frequency of the prominent vibrational interval is already known to