𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vibronic coupling and the duschinsky effect in benzene

✍ Scribed by F. Metz; M.J. Robey; E.W. Schlag; F. Dörr

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
430 KB
Volume
51
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Explicit consideration of mode mixing (Duschinsky effect) is necessary to interpret the vibronic intensities in the oneand two-photon spectra of the electronically forbidden 'Bzu e 'Al8 transition in benzene. Good agreement with experiment is obtained by using a set of excited state normal coordinates derived from experiment.

📜 SIMILAR VOLUMES

Vibronic coupling in electronic transiti
Vibronic coupling in electronic transitions with significant Duschinsky effect
✍ Andrea Peluso; Fabrizio Santoro; Giuseppe Del Re 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB

Conceptual and mathematical difficulties arise in the study of transitions between vibronic states belonging to crossing Born᎐Oppenheimer hypersurfaces with significantly different positions and shapes of the minimum-energy nuclear configurations Ž . Duschinsky effect . This article presents an anal

Vibronic coupling effects in the ozone c
Vibronic coupling effects in the ozone cation
✍ H. Müller; H. Köppel; L.S. Cederbaum; T. Schmelz; G. Chambaud; P. Rosmus 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 737 KB

A multi-mode vibronic coupling Hamiltonian which includes coupling terms up to second order in the nuclear displacements is used to study theoretically the vibronic interactions between the ground and tirst excited electronic states of the ozone cation, 0:. The relevant coupling constants rely on pr