Vibrations of a diatomic molecule in the generalized force representation
✍ Scribed by J. Plíva; S. Toman; F. Jenč
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- English
- Weight
- 600 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
The problem of the determination of the vibration-rotation eigenvalue in diatomic molecules is considered. An eigenvalue equation totally independent from the eigenfunction is written for any potential, analytical or numerical. This equation uses uniquely the vibration-rotation canonical functions;
The commutator perturbation method, an algebraic version of the Van Vleck-Primas perturbation method, expressed in terms of ladder operators, has been applied to solving the eigenvalue problem of the Hamiltonian describing the vibrational-rotational motion of a diatomic molecule. The physical model
## Accurate quantum mechanical transition probabilities for vIbrationa to vibrational and vibrational to translational cncr- gy txm\fcr in collmcar colliaons of two hydrogen molecules were calculated for a model pootentki by numerica integration of the Sduodmgcr equation. The accuracy of these cal