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Vibrations and Thermodynamics of Clusters of Polycyclic Aromatic Hydrocarbon Molecules: The Role of Internal Modes

✍ Scribed by Rapacioli, Mathias; Calvo, Florent; Joblin, Christine; Parneix, Pascal; Spiegelman, Fernand


Book ID
119991792
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
373 KB
Volume
111
Category
Article
ISSN
1089-5639

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A treatment of vibrational relaxation of impurity molecules in host solids is given, which introduces two improvements over existing theories: (i) The librational degree of freedom is taken into consideration. (ii) Local translational modes at the impurity site are included in the treatment. A reali