✦ LIBER ✦

Vibrationally resolved Si 2p photoabsorption spectrum of SiF4

✍ Scribed by R. Püttner; M. Domke; K. Schulz; G. Kaindl

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 608 KB
Volume: 250
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)01414-4

No coin nor oath required. For personal study only.

✦ Synopsis

A high-resolution study of the Si2p photoabsorption spectrum of gas-phase SiF, is reported. In the excitation region of the Rydberg orbitals, vibrational substates from symmetric stretching vibrational modes were resolved, which were described on the basis of a Franck-Condon analysis resulting in vibrational energies and equilibrium interatomic distances of the core-excited molecule. The natural lifetime width of the Si 2p core excitation amounts to 85 meV, a value that is substantially larger than the theoretically predicted one.

📜 SIMILAR VOLUMES

Vibrational effects in the Si 2p pre-edg

Vibrational effects in the Si 2p pre-edge photoabsorption spectroscopy of SiH4, SiD4, Si2H6 and Si3H8

✍ D.G.J. Sutherland; G.M. Bancroft; J.D. Bozek; K.H. Tan 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 630 KB

High-resolution (0.05 eV) Si 2p pre-edge photoabsorption spectra of SiH,, SiD,, S&H6 and S&Ha have been recorded. The spectra show a large number of peaks due to Si 2pdRydberg transitions, along with rich vibrational structure. The spectrum of SiD4 has been very useful in determining the exact posit