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Vibrationally resolved photoelectron angular distributions for H2

โœ Scribed by E.D. Poliakoff; J.L. Dehmer; P.M. Dehmer; A.C. Parr


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
488 KB
Volume
96
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The phutocIcctron 3x1 mmclry pammeter, 8. is reportcvf for individual vibrational levels of H$X 2 s>_ formed by phoro-wn~~tmn of 112(,X ' -> at w~\clengrhs of 736,584,461 and 304 A. At 584 A. p exhibits a monotonic mcrease xbith vihrstiorul qu.mrum nz:bcr (dccrwsinL: photoelccrron kinetic energy) confirming the trend predicted by Itikawa. * Work \upporred b) the US Dcp.utment of Energy and the Office oi N,tvaI Rcsrarch


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We present a theoretical study of O(ka) and O(k 2 a 2 ) corrections to the dipole approximation in photoionization of rare gas atoms, where k is the magnitude of the photon wave vector and a is the radius of the ionized subshell. In the dipole approximation, the photoelectron angular distribution is