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Vibrational versus electronic first hyperpolarizabilities of mono- and disubstituted benzenes: An ab initio coupled Hartree–Fock investigation

✍ Scribed by Benoît Champagne


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
202 KB
Volume
65
Category
Article
ISSN
0020-7608

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✦ Synopsis


Hartree᎐Fock 6-31G level by using coupled Hartree᎐Fock and the double harmonic v Ž . e Ž . oscillator approximations, respectively. Although the ␤ 0 r␤ 0 ratio is slightly larger

Ž . than unity and rather constant with respect to the substituent s , it turns out, for the e Ž . monosubstituted compounds, that the variations of ␤ 0 upon substitution can be most L v Ž . accounted for by the mesomeric effects, whereas for ␤ 0 , the inductive effects are also L