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Vibrational study of tellurium and rhenium siloxane derivatives, (tBu)2SiO2(TeCl2-μ-Cl2-TeCl2) and (tBu)2Si(OReO3)2

✍ Scribed by A. Haoudi-Mazzah; P. Dhamelincourt; A. Mazzah; M. Lazraq

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
247 KB
Volume
29
Category
Article
ISSN
0377-0486

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✦ Synopsis

By a condensation reaction of with and respectively, tellurium and rhenium siloxy tBu 2 Si(OH) 2 TeCl 4 Re 2 O 7

, derivatives, were prepared. They were crystallized and identiÐed by the usual physical techniques (1H, 13C, 29Si and 125Te NMR spectroscopy, x-ray di †raction and mass spectrometry). Raman and IR spectra were recorded, which conÐrmed the structure obtained by x-ray di †raction for both compounds.

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