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Vibrational study of 15N and D substituted guanines in acid and basic solutions

✍ Scribed by Jean-Maurice Delabar

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
668 KB
Volume
7
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

Acid and basic solutions of ^15^N and D substituted guanines have been investigated by infrared and Raman spectroscopy. Monoanion and dianion formation have been followed by spectra changes; N^7^, N^9^H tautomery has also been studied by comparing with methylated derivatives. Assignment of the band frequencies have also been proposed. Analysing ^15^N results have permitted precise comparisons between the neutral form spectra and the anionic or cationic form spectra.Abbreviations used: IUPAC‐IUB abbreviations are used throughout: m^7^−Gua or m^7^ ‐guanine: 7‐methyl‐guanine, etc.

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