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Vibrational studies of reactive intermediates of aromatic amines. 2. Free-radical cation and dication resonance Raman spectroscopy of N,N,N',N'-tetramethylbenzidine and N,N,N',N'-tetraethylbenzidine

✍ Scribed by Guichard, V.; Bourkba, A.; Poizat, O.; Buntinx, G.


Book ID
118745807
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
878 KB
Volume
93
Category
Article
ISSN
0022-3654

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The radical cation of N,Ndimethylpiperazine is investigated by resonance Raman spectroscopy and ab initio calculations. The calculations strongly support the assignment of the vibrational spectrum to a chair conformation. It is shown that a dramatic geometry relaxation following ionization allows a