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Vibrational structure in the luminescence of the [TiOF5]3− octahedron

✍ Scribed by G. Blasse; G.J. Dirksen; G.J. Pausewang; R. Schmidt

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 225 KB
Volume: 88
Category: Article
ISSN: 0022-4596
DOI: 10.1016/0022-4596(90)90259-z

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The crystal structure and the luminescent properties of TlZn(PO 3 ) 3 are studied with respect to Tl ؉ stereochemistry. In this polyphosphate the Tl ؉ ions are located in tunnels created by the zinc polyphosphate network [Zn(PO 3 ) 3 ]. Actually the thallium atoms are found in a disymmetric con5gura