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Vibrational spectrum of crystalline cyclopentanone

✍ Scribed by R. Cataliotti; G. Paliani

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
337 KB
Volume
20
Category
Article
ISSN
0009-2614

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✦ Synopsis

Infrared and Raman spectra of liquid and solid cyciopentanone have been studieg. Spectroscopic ecidence shows that the molecule undergoes a solid state phase transition at 168'K. Tile crystalline form stable below this temperature is ordered and close-packed; its infrued and Raman spectra have been interpreted assuming that cyclopentanone crysttiizes in the C:h or Cj centrosymmetric space goups * This is also the point CC view of Jones and his coworkers, who are presently engaged into a normal-coordinate analysis of CPN treated as a rigid body of C2 symmetry [ 81.

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