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Vibrational Spectrum and Electronic Structure of the [B11H11]2– Dianion

✍ Scribed by Elena G. Kononova; Larissa A. Leites; Sergey S. Bukalov; Irina V. Pisareva; Igor T. Chizhevsky; John D. Kennedy; Jonathan Bould


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
182 KB
Volume
2007
Category
Article
ISSN
1434-1948

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Undecaborates M2[B11H11]: Facile Synthes
✍ O. Volkov; W. Dirk; U. Englert; P. Paetzold 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 228 KB 👁 1 views

closo-Undecaborates were synthesized by the deprotonation of B 11 H 13 (SMe 2 ) with LitBu in thp or K [BHEt 3 ] in thf, [Li(thp) 3 ] 2 [B 11 H 11 ] and K 2 [B 11 H 11 ] being obtained in 83 and 93% yield, respectively. K 2 [B 11 H 11 ] can be transformed into A 2 [B 11 H 11 ] with the corresponding

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✍ O. Volkov; W. Dirk; U. Englert; P. Paetzold 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 1 views

Undecaborates M 2 [B 11 H 11 ]: Facile Synthesis, Crystal Structure, and Reactions. -Crystal structure analysis of (III) (space group P2 1 /c, Z = 4) reveals a rather distorted octahedron for the [B 11 H 11 ] 2-anion, whereas the corresponding octahedron in (VIIb) (space group ) exhibits a structure