Vibrational spectroscopy of the electrochemical interface by visible infrared sum frequency generation
β Scribed by A. Tadjeddine; A. Peremans
- Publisher
- Elsevier
- Year
- 1996
- Tongue
- English
- Weight
- 767 KB
- Volume
- 409
- Category
- Article
- ISSN
- 1572-6657
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
We present the first application of infrared-visible sum-frequency generation to studies of liquid/solid interfaces. The spectra in the CH stretch region of a saturated monolayer of octadecyltrichlorosilane (OTS) adsorbed at various interfaces bound by a fused silica substrate were measured and comp
Sum frequency generation (SFG) spectroscopy has been applied to study the electrochemical reduction of 4-(4-(diethylamino)styryl)-N-methylpyridinium iodide (D289) at the electrolyte-Si(111) interface. By employing electrically conductive Si(111) as the substrate and choosing the proper excitation sy
We show that the measurement of the absolute phase of the infrared-visible sum frequency susceptibility of a monolayer of molecules of lcnown orientation determines the relative sign of the dipole moment derivative and the polarizability derivative with respect to the normal mode. With the sign of t