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Vibrational spectroscopy of nonequivalent CH bonds in liquid cis- and trans-3-hexene

✍ Scribed by Carlos Manzanares I; Victor M. Blunt; Jingping Peng


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
871 KB
Volume
49
Category
Article
ISSN
1386-1425

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Two conformations of cis-cyclohexyl-10-crown-3 were detected in solution below 250 K using 1H NMR at 400 MHz and 13C NMR at 100 MHz. Chemical shift assignments were facilitated by spectra of two dideuterio derivatives. From relative peak area measurements, the conformation with the unit OÈCH 2 ÈCH 2