Vibrational spectroscopy at high pressures—57 [1]. Phosphonitrilic chloride trimer and tetramer

✍ Scribed by David M. Adams; Andrea C. Shaw

• Book ID: 103907661
• Publisher: Elsevier Science
• Year: 1991
• Tongue: English
• Weight: 337 KB
• Volume: 47
• Category: Article
• ISSN: 1386-1425
• DOI: 10.1016/0584-8539(91)80250-m

✦ Synopsis

Ababct-Raman and IR spectra at high pressures are reported for (PNClJ,and (PNCQ.,. The trimer exhibits a second order phase transition near 22 kbar to a structure of probable monoclinic symmetry, whilst the tetramer shows evidence of a similar change near 10 kbar.