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Vibrational spectroscopic studies of tervalent hexa-aqua cations: oriented single-crystal Raman spectra between 275 and 1 200 cm?1 of the caesium rhodium alums, CsRh(SO4)2�12H2O, CsRh(SeO4)2�12H2O, and CsRh(SO4)2�12D2O

✍ Scribed by Best, Stephen P.; Beattie, James K.; Armstrong, Robert S.; Braithwaite, Gerard P.

Book ID: 118247044
Publisher: The Royal Society of Chemistry
Year: 1989
Tongue: English
Weight: 875 KB
Volume: 9
Category: Article
ISSN: 1472-7773
DOI: 10.1039/dt9890001771

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## Abstract Low‐temperature, polarized, single‐crystal Raman spectra of the β‐alums CsM(SO~4~)~2~. 12H~2~O (M = Mo or Ru) and their deuterated analogues were recorded between 275 and 1200 cm^−1^. The internal modes of sulphate and [M(OH~2~)~6~]^3+^ and the external modes of water coordinated to the