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Vibrational spectroscopic investigation of mono and tris-2,2′-bipyridyl metal(II) tetracyanonickelate compounds

✍ Scribed by Sevim Akyüz; Ayşen Erbolukbas Ozel; J. Eric D. Davies; Meriç Bakiler


Publisher
Springer Netherlands
Year
1996
Tongue
English
Weight
289 KB
Volume
26
Category
Article
ISSN
0923-0750

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C Chemical shifts are reported for the ruthenium(II) tris complexes of thirteen 2,Z-bipyridyls and three 1,lO-phenanthrolines and for the osmium(]") bris complexes of five 2,2'-bpyridyls. Chelation induced shifts -&3 are discussed in terms of models for n back-bonding. -C NMR is shown to be a conven