Vibrational spectral studies of ion-ion and ion-solvent interactions. III. Zinc nitrate in water/acetonitrile mixtures
β Scribed by Yu-Keung Sze; Donald E. Irish
- Publisher
- Springer US
- Year
- 1979
- Tongue
- English
- Weight
- 729 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0095-9782
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π SIMILAR VOLUMES
Conductance measurements are reported for several salts in binary aqueous mixtures containing up to 60 mole y0 sulfolane, 20 mole % acetonitrile and 20 mole % dimathylsulfoxida. The variations of R = (A$~o),/(A~qo), with solvent composition have been compared with those observed in other water-rich
The equilibrium quotients for the formation of Co(NH3) SCl2+ from Co(NH3) 50Hz3+ and CI1were 3.74 f 0.25 M-' and 6.07 f 0.54 M-' at 45.OoC in 10: 1 mole ratio water: dimethyl sulfoxide and in 25 w/w yo aqueous ethanol, respectively, and those for the formation ofthe ion pair C O ( N H ~) ~O H ~~+ .