## Abstract A valence force field has been refined for singleβchain polyglycine II using the known structure and four isotopic derivatives. The calculated frequencies are in good agreement with the observed. The force field is compared with that derived from polyglycine I and for the nylons.
Vibrational spectra of polyglycine II
β Scribed by R.D. Singh; V.D. Gupta
- Book ID
- 113372600
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 568 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1386-1425
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π SIMILAR VOLUMES
## Frequency distribution function for helical conformation of polyglycine (P.G. II) is obtained from &p&don curves and is compared with that obtained from inelastic neutron scattering in the one phonon and cubic approximation.
The laser-excited Raman spectrum of helical polyglycine I1 has been ob1,ained. Oligomers of polyglycine are in the planar zigzag conformation and their llamati spectra are indicative of the spectrum of polyglycine I. The Raman spectra of polyglyciries have bands complementary to the infrared which
Iiifrared spectra of polyglycines 1 and I1 obtained a t -170Β°C. have been compared with those obtained a t room temperature. The ,changes in frequency of some of the C-H stretching bands are consistent with the earlier suggestion that C-H --.O=C hydrogen bonds are present in the structure of polygly