✦ LIBER ✦
Vibrational spectra of carboxylato complexes—VI. Isotopic substitution in the mixed-metal trinuclear complexes [FeIII2NiIIO(OOCCH3)6L3]
✍ Scribed by L. Meesuk; U.A. Jayasooriya; R.D. Cannon
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 439 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1386-1425
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✦ Synopsis
Infrared and Raman spectra of the complexes [Fe "',Nil'O(OOCCH,),L,], L = C,H,N and H,O, are reported. Assignments in the region 800 to 200 cm _ I are made on the basis of substitution of "0 for I60 (central oxygen) and deuteration. In particular, the two components of the in-plane asymmetric vibration v,,(Fe,NiO) are identified at 722 and 565 cm I.