✦ LIBER ✦

Vibrational spectra of bis(L-ornithinium) chloride nitrate sulfate

✍ Scribed by S. Ramaswamy; R. K. Rajaram; V. Ramakrishnan

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 129 KB
Volume: 36
Category: Article
ISSN: 0377-0486
DOI: 10.1002/jrs.1257

No coin nor oath required. For personal study only.

✦ Synopsis

The Raman and infrared absorption spectra of 2(C 5 H 14 N 2 O 2 2+ )•Cl -•NO 3 -•SO 4 2-crystal containing three anions were recorded at room temperature and were interpreted in the light of crystal structure data. The presence of a carbonyl group was identified. The carboxylic group was found to exist as COOH. The formation of O -H• • •O, N -H• • •O and N -H• • •Cl asymmetric hydrogen bonds contributes considerably to the crystal cohesion and is responsible for the changes in the position and intensity of several bands. The vibrational spectra show that the anions were found to coordinate through hydrogen bonding interactions to other ligands in the crystal. The lattice wavenumbers of the halide radical (chlorine anion) were also assigned in terms of hydrogen bond vibrations.

📜 SIMILAR VOLUMES

Bis(l-ornithinium) chloride nitrate sulf

Bis(l-ornithinium) chloride nitrate sulfate

✍ Ramaswamy, S. ;Sridhar, B. ;Ramakrishnan, V. ;Rajaram, R. K. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 279 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.039 wR factor = 0.098 Data-to-parameter ratio = 9.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Vibrational spectra of l-arginine nitrat

Vibrational spectra of l-arginine nitrates

✍ A.M. Petrosyan; R.P. Sukiasyan 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 253 KB

Crystals L-arginineAE'HNO 3 AE0.5H 2 O and L-arginineAE2HNO 3 have been studied by attenuated total reflection Fourier transform infrared (FTIR ATR) and Fourier transform Raman spectroscopy with taking into account their crystal structures.

The vibrational spectra of aqueous nitra

The vibrational spectra of aqueous nitrate solutions

✍ L. V. Volod'ko; Lieh Than Huoah 📂 Article 📅 1968 🏛 Springer US 🌐 English ⚖ 393 KB

Vibrational spectra and structure of bis

Vibrational spectra and structure of bis-π-allylnickel

✍ T. B. Chenskaya; L. A. Leites; V. T. Aleksanyan; L. S. Isaeva; L. N. Lorens 📂 Article 📅 1974 🏛 SP MAIK Nauka/Interperiodica 🌐 English ⚖ 360 KB

Single-column ion chromatography for the

Single-column ion chromatography for the determination of chloride, sulfate, and nitrate in water

✍ Martínez, L. I. ;Passaré, A. F. 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB 👁 1 views

Vibrational spectroscopic study of the s

Vibrational spectroscopic study of the semiorganic nonlinear optical crystal bis(thiourea)cadmium chloride

✍ V. Venkataramanan; H. L. Bhat; M. R. Srinivasan; P. Ayyub; M. S. Multani 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 400 KB 👁 2 views

Polarized Raman and infrared spectra of bis(thiourea)cadmium chloride, a novel semiorganic nonlinear optical crystal, were recorded to determine the symmetries of molecular vibrations. The observed Raman and infrared bands are assigned to molecular vibrations of thiourea, cadmium-sulphur and cadmium