Vibrational spectra and the ferroelectric phase transition of colemanite
โ Scribed by R. F. Gallup; L. B. Coleman
- Publisher
- Springer-Verlag
- Year
- 1990
- Tongue
- English
- Weight
- 351 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0342-1791
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โฆ Synopsis
The infrared and far infrared (10-4000 cm-1) polarized, single crystal reflectivity of the calcium borate mineral colemanite, CaB30~(OH)3"HzO, have been measured at room temperature and at several temperatures below the ferroelectric phase transition at approximately 270 K. Over the entire frequency range studied, only minor spectral changes are seen at the ferroelectric phase transition.
๐ SIMILAR VOLUMES
## Abstract The vibrational spectra of NaNH~4~SO~4~ ยท 2H~2~O (SASD) and its 5% deuterated system were observed in the region of the OโX and NโX stretches (X = H or D) over the temperature range 300โ25 K. A similarity was found in the Raman spectral features associated with water molecules at room t