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Vibrational spectra and structure of AlCl3NH3 and molten mixtures with MCl-AlCl3 (M = Li, Na, K OR Cs)

✍ Scribed by T. Østvold; E. Rytter; G.N. Papatheodorou


Book ID
108428872
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
959 KB
Volume
5
Category
Article
ISSN
0277-5387

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The kinetics of aluminium deposition from NaCI-AICI 3 , KCI-AICI 3 and CsCI-AICI 3 melts (C,rlc1 . = 3 x 10 -'-1 x 10 -3 mol em -3 ) was studied using the chronopotentiometric technique . It was found that in the system NaCI-AIC 3 the reduction of AI(III) species is controlled by diffusion only, whi