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Vibrational spectra and normal coordinate analysis of Ni and Zn complexes with 1-(2-pyridylazo)-2-naphthol

✍ Scribed by Piotr M Drożdżewski

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
660 KB
Volume
45
Category
Article
ISSN
1386-1425

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✦ Synopsis

Infrared and resonance Raman spectra of Ni(PAN), and Zn(PAN), (where PAN denotes l-(2pyridylazo)-2-naphthol)

have been measured in the solid state. In addition, the nickel complex dissolved in CS, has also been investigated

by Raman spectroscopy at room temperature and 16 K. A normal coordinate analvsis was performed to characterize the observed vibrational transitions in terms of potential energy distribution. _

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The infrared and Raman vibrational spectra of 1,1,2,2-tetrachlorodisilane and its (Cl -isotopomer were measured and assigned with the aid of normal coordinate analyses and also ab initio RHF Cl 2 DSiSiDCl 2 geometry optimizations and harmonic wavenumber calculations using the GAMESS quantum chemist