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Vibrational spectra and metal?metal bonding in the hexahalogenodigallate(II) ions, Ga2X6 2?(X = Cl, Br, and I)

✍ Scribed by Evans, Christopher A.; Tan, Kang Hai; Tapper, Spencer P.; Taylor, Michael J.


Book ID
121380095
Publisher
The Royal Society of Chemistry
Year
1973
Tongue
English
Weight
538 KB
Volume
9
Category
Article
ISSN
1472-7773

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Bond strengths of the gas-phase cluster
✍ Kenzo Hiraoka; Susumu Fujimaki; Kazuo Aruga; Shinichi Yamabe πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 467 KB

Thermodynamic quantities, AH:\_ ,,\* and AS:\_ ,,", for the clustering reactions, X-(CSI),\_,+CSz=X-(CS,),, X=F, Cl, Br and I, were measured with a pulsed electron-beam high-pressure mass spectrometer. A large binding energy, 35.0 kcal/mol, for F-...CS2 has been obtained, whereas those for other X-.