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Vibrational Spectra and Gas Phase Structure of N -Cyanoimidosulfurous Difluoride, NCNSF 2

✍ Scribed by Alvaréz, Rosa S. M.; Cutin, Edgardo H.; Della Vedova, Carlos O.; Mews, Rüdiger; Haist, Ralf; Oberhammer, Heinz


Book ID
127334678
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
48 KB
Volume
40
Category
Article
ISSN
0020-1669

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The vapor phase structure of ( C H 3 0 ) S [ I ] has been investigated by electron diffraction and ab initio MO calculations, which both result in a C2 symmetry for the most stable geometry, the C, conformer being less stable by about I2 Wlmol. The torsional barrier for rotation about one SO bond wa