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Vibrational spectra and force constants of symmetric tops—XXX. Rovibrational spectra of CF3 35Cl in the ν5, ν1 + ν5 and ν2 + ν5 region

✍ Scribed by H. Bürger; R. Grassow; A. Ruoff

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 532 KB
Volume: 39
Category: Article
ISSN: 1386-1425
DOI: 10.1016/0584-8539(83)80089-0

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✦ Synopsis

The gas phase i.r. spectra of monoisotopic CF, 35C1 have been recorded with a resolution of 0.04 cm-' in the region of vs, 561.10(l), v2 + v5, 1344.86(l), and vr + vs, 1666.58(3) cm-'. Band origins have been determined unambiguously from the shape of the respective RQ, branch which is affected by 1( f 2, & 2) resonance. A rotational analysis has been performed by means of least squares refinement and band contour simulation methods. and vibration-rotation interaction parameters o$, cz," and qi +) have been determined.

Hot bands of vg have been detected and assigned.

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