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Vibrational satellites of γ-transitions of nuclei in molecules

✍ Scribed by V.S. Letokhov

Book ID
103768216
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
149 KB
Volume
46
Category
Article
ISSN
0375-9601

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📜 SIMILAR VOLUMES

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✍ A. Warshel; M. Karplus 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 711 KB

A general approach is presented for calculating the vibronic structure (Fran&-Condon factors) of electronic transitions in conjugated molecules. Applications to the lowest &owed ITIT\* transition of ethylene, 1,3-cyclohexadiene, 1,3,5hesatriene, and F\_ionone are given.

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Relative shif= of the central and satellite lransllion lines determine :he precrsc iosotropic chemical shlfls of I = 5/2 and 9/2 quadrupolar nuclei in solids The sarelhle transition is conveniently measured through the nxatron sidebands.