Vibrational frequencies in excited and ionized states are ca.IcuIated for primary aromatic hydrocarbons, on the basis of MO cdcuhtions of transition energies and normal coordhate ulculations for ground state moIecuIes. Results are in good agreement with experiment-Specific activities of certain type
Vibrational relaxtion in excited electronic states of aromatic hydrocarbons
β Scribed by Kee-Ju Choi; Michael R. Topp
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 615 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Tune-resolred expenments are reported showing kinetic evidence for vibrational relaxation of electronically excited mokcules in solution at room temperature. The experiments mvolve higher electronic states of 3,4,9,10~iibenzpyrene. Data are consistent with slow vibrational relaxation (== 15 ps), similar to that for ground state species.
π SIMILAR VOLUMES
The vibrational energy relaxation (VER) of polyatomic molecules has been the central issue in many of the chemical reactions in condensed phase [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17] as well as in gas phase . The vibrational energy introduced to the molecule is immediately redis
Evidence rs presented that the excited singlet and triplet states of aromatic hydrocarbons are oxidised by methyi viologen (hlV2>. Rate constants for electron transfer from triplet naphthalene, anthracene, phenanthrene and fluoranthene are close to diffusion-controlled whereas those for triplet l-cy