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Vibrational relaxation of NH2|X2B1(O, v2, O)| radicals

✍ Scribed by Tian-Xiang Xiang; Karl-Heinz Gericke; Lourdes M. Torres; William A. Guillory

Book ID: 103665163
Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 632 KB
Volume: 101
Category: Article
ISSN: 0301-0104
DOI: 10.1016/0301-0104(86)87031-8

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The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u