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Vibrational relaxation of ND2(0,1,0) radicals studied by fast magnetic-field-jump time-resolved LMR

✍ Scribed by A.I. Chichinin; L.N. Krasnoperov

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 579 KB
Volume: 115
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80040-3

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✦ Synopsis

A method of smdyiqg vlbrauonal relaxation of gaseous free radicals has been developed using the ume-resolved LMR tecbruque. The LMR sgnal saturation kinetics IS measured under a fasl adJustmen LO the maximum of rhe fit denvatwe of the absorptirln bae with the help of a fast magnetic field JLIIUP (80 G. 10 ps) The vibrational relaxanon rate U_XKUIHS (V-V plus V-T)bavebeen measured forND~(O.l,O)onND,. CF, and Ar. (2.7&-1)x10-~', (1 9fO4)xlO-" and (2 4&O7)xiO-'4 cd/s. respecwely. (f2a) The matm element of the wbrational tinon moment for ND, Ye vibratloz is estimated IO be 0.056 *O 02 D.

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