✦ LIBER ✦
Vibrational relaxation of hydrogen-bonded species in solution: analysis of the vσ(OHṫN) vibration of phenol-pyridine
✍ Scribed by J. Yarwood; R. Ackroyd; G.N. Robertson
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 479 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Independent estxmates have been obtained for the dampms constant 7 of the v,(OH,. N) mode of phenol-pyridme m carbon tetrachloride, by analysing the far-mfrared p. and the mid-mfrared t~s band proffies. The e&mates of y are in-compatl%le Possible causes of the discrepancy, and their theoretical implications, are dlscussed. l_ introduction We have recently developed [ 1,2j and tested f3, 4] a stochastic theory of the broadening of the v,(XEI) bands of hydrogen-bonded complexes in solution by vibrational phase relax&tion_ We assume that the low-frequency v,(XH...Y)