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Vibrational Relaxation of Highly Vibrationally Excited O 3 in Collisions with OH

✍ Scribed by Zhang, Lei; Luo, Pingya; Huang, Zhiyu; Chen, Hong; Varandas, António J. C.


Book ID
118178572
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
118 KB
Volume
112
Category
Article
ISSN
1089-5639

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The measurement of vibrational state-to-state population transfer for a highly vibrationally excited polyatomic molecule (cym\* 9600 cm-i) is reported. This work combines direct overtone vibration excitation with LIF via the A 'A" state of HCN to obtain the rate k= (2.4kO.3) x 10-i\* cm' molecule-'