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Vibrational rate enhancement in the X(=Cl, Br) + H2 HX + H reactions

✍ Scribed by L.B. Sims; L.R. Dosser; P.S. Wilson


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
303 KB
Volume
32
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


Vibrational rate enhancement in the reac
✍ R Zellner; W Steinert πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 317 KB

The rate constant for the reaction between OH and vibrationally excited H2, OH + H 2 (v = 1) ~ H20 + H, has been measured directly at 298 K. kol is found to be (7.5 -+ 3) X 10 -13 cma/molecule s, corresponding to a vibrational rate enhancement ofkol/koo = (1.2 -+ 0.4) X 102.

Vibrational enhancement of the reaction
✍ I. Schechter; R. Kosloff; R.D. Levine πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 496 KB

The cone or acceptance for H+H= reactive collisions is shown Lo open up upon strelching of the H, bond. AL a given wtmslational energy, the sreric faclor is thus much larger for vibrzkonally cxcircd rcngems as demonswatcd by class&l IrajccLoq compulorions for H+ D?(U) and D+Hz(o). AI a given lolaI c

Kinetic study of the reactions of CL and
✍ Shawn P. Heneghan; Sidney W. Benson πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 393 KB πŸ‘ 1 views

The reactions of C1 and Br atoms with HzOz have been studied in the range of 300-350 K using the very-low-pressure-reactor technique. It was found that metathesis to produce HX and H02 is the only significant process (199%). For the reaction of Br 2 Br + HzO2 + HBr + HOz k z (300 K) = 1.3 f 0.45 X a