Vibrational raman optical activity spectra recorded in perpendicular polarization

✍ Scribed by W. Hug; H. Surbeck

• Publisher: Elsevier Science
• Year: 1979
• Tongue: English
• Weight: 585 KB
• Volume: 60
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(79)80012-3

✦ Synopsis

Raman opticaI activity spectra have been recorded for the fmt time in both polarization directions with a newly constructed spectrometer_ It is showa that kxiuable information can be gained on the importance of individual tensor invariants appearing in the theoretical formuIae of the effect.

1 _ Signifkance and measurement problems of Raman optical activity

Raman optical activity appears to be the currently most promising approach to an eventual routine determination ofvibrational optical activity. AI-I order of magnitude more of StereochemicaI information on chiral molecules can be expected by its knowledge than from