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Vibrational polarizabilities for H2+, H2 and N2

✍ Scribed by David M Bishop; Brenda Lam

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
348 KB
Volume
134
Category
Article
ISSN
0009-2614

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✦ Synopsis

General formulae for the purely vibrational contributions to the static polarizabilities A,, or, B,, 0, 76, and CM, ys are presented. As specific examples, the vibrational contributions to the 7, B, and C tensors for H;, Ha and N2 are calculated. In addition values of the hexadecapole moment for Hz at a series of internuclear distances are given.

Polarizability tensors are most conveniently defined by writing the energy of a molecule perturbed by a dis tant external charge as [l]

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